![]() ![]() List of thirty-three substances because he believed they were compounds, although the “nature of the principles which enter into their composition is still unknown.” He suspected that they might contain nitrogen, since it had been shown that ammonium contained that element. Sir Humphry Davy - portrait in Royal Institution, London He explained that he did not include the “fixed alkalis” in his With Lavoisier’s amazing insight (see the “True Elements”), it may seem strange that he did not include sodium and potassium in his list of the elements. But the true nature of the two alkalis remained unknown. The “cubic saltpetre gunpowder” flashed yellow and the “prismatic saltpetre gunpowder” flashed blue. Several other investigators continued to characterize the two alkalis, with the most definitive account by Marggraf in 1759 who prepared very pure samples of “cubic saltpetre” and “prismatic saltpetre” from which he made gunpowder (from sulfur, charcoal and saltpetre). Stahl (the promoter of phlogiston see previous chapter on the “True Elements”) formally distinguished between “natural alkali” (soda) and “artificial alkali” (potash) in 1702. In 1683 Johnan Bohn prepared “cubic saltpetre” (sodium nitrate) from a mixture of salt and nitric acid, which he recognized as different from the ordinary saltpetre (potassium nitrate) by the shape of its crystals and its taste. Only gradually was it recognized that there was a difference between “plant alkali” (potash, potassium carbonate), obtained from the ashes of plants, and “mineral alkali” (soda, sodium carbonate), found in salt flats and evaporated seawater. Historically, the distinction between sodium and potassium was not made easily. ![]()
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